You can find out the right tyre pressures for your car in the handbook or on a sticker inside the fuel filler flap or driver's door. Remember that pressures are quoted for cold tyres and that you will probably have to increase pressures when you carry heavy loads.
In general the handbook or stickers will show two figures, one for 'normal' use and a higher figure for full loads. Be sure to adjust the pressures to suit the conditions.
If you can't find details of the correct tyre pressures it's best to contact the vehicle manufacturer - their websites usually give details of customer services departments. You will need to make a note of the size of the tyres fitted - taken from the sidewalls - as well as the make/model and registration number.